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When Agent Jemma Simmons is captured by Hydra during a firefight, she ends up sharing a cell with The Winter Soldier... Captain America: The Winter Soldier, Marvels Agents of S.H.I.E.L.D. Based solely on the movie version of Bucky Barnes. Takes place right after Agents of SHIELD episode Turn, turn, turn. Pairing "WINTER BIOCHEMIST" (or "WINTERJEM") The Winter Soldier/Jemma Simmons