The Amazing Spider-Man: SHEILD Opporative

When taking a visit to Oscorp to clean out Gwen's office. He receives... unbearable news... Peter's more of an emotional wreak than he was prior to. Which causes him to go off on S.H.I.E.L.D. and repeatedly rejects the Avengers invite. Once Black Widow steps in, persistently trying to persuade Peter into joining the team... things change, and not all turns out according to plan.